AcidityMediumQuestion 730009
Question
Acidity of alcohols follows the order:
- ACH₃OH > C₂H₅OH > (CH₃)₂CHOH > (CH₃)₃COHCorrect
- B(CH₃)₃COH > (CH₃)₂CHOH > C₂H₅OH > CH₃OH
- CAll equal
- Dt-BuOH > MeOH
Correct answer
CH₃OH > C₂H₅OH > (CH₃)₂CHOH > (CH₃)₃COH
Explanation
Alkyl groups donate electron density and destabilise the alkoxide conjugate base. Thus acidity decreases with greater alkyl substitution: CH₃OH > C₂H₅OH > (CH₃)₂CHOH > (CH₃)₃COH.