Periodic law
1. Modern periodic law states that properties of elements are periodic functions of:
- A. atomic number (Correct)
- B. atomic mass
- C. neutron number
- D. molar mass
Explanation: Modern periodicity is based on atomic number.
Period
2. Horizontal rows in the periodic table are called:
- A. periods (Correct)
- B. groups
- C. blocks
- D. series
Explanation: Periods run left to right.
Group
3. Vertical columns in the periodic table are called:
- A. groups (Correct)
- B. periods
- C. blocks
- D. shells
Explanation: Groups contain chemically similar elements.
Atomic radius
4. Across a period, atomic radius generally:
- A. decreases (Correct)
- B. increases
- C. remains constant
- D. first increases then decreases
Explanation: Effective nuclear charge rises across a period.
Atomic radius
5. Down a group, atomic radius generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes zero
Explanation: Additional shells are added down a group.
Ionization enthalpy
6. Across a period, first ionization enthalpy generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes negative
Explanation: Smaller size and higher nuclear charge hold electrons more tightly.
Electron gain enthalpy
7. Halogens generally have:
- A. highly negative electron gain enthalpy (Correct)
- B. positive electron gain enthalpy
- C. zero electron gain enthalpy
- D. the lowest electronegativity
Explanation: They strongly attract an extra electron.
Electronegativity
8. Fluorine has the highest:
- A. electronegativity (Correct)
- B. atomic radius
- C. metallic character
- D. number of shells
Explanation: Fluorine is the most electronegative element.
Metallic character
9. Metallic character across a period generally:
- A. decreases (Correct)
- B. increases
- C. remains same
- D. becomes maximum in noble gases
Explanation: Elements become less willing to lose electrons.
Metallic character
10. Metallic character down a group generally:
- A. increases (Correct)
- B. decreases
- C. remains same
- D. becomes zero
Explanation: Larger atoms lose electrons more easily.
Valency
11. Valency across a period first increases and then:
- A. decreases (Correct)
- B. stays fixed
- C. becomes zero only
- D. doubles
Explanation: It follows the tendency to gain or lose electrons toward noble-gas configuration.
Oxides
12. Across a period, oxides generally change from:
- A. basic to acidic (Correct)
- B. acidic to basic
- C. neutral to metallic only
- D. basic to amphoteric to basic
Explanation: Metallic oxides are basic while non-metallic oxides are acidic.
Shielding
13. The main reason effective nuclear charge rises across a period is:
- A. shielding does not increase enough to offset nuclear charge (Correct)
- B. mass number increases only
- C. all electrons stay in same orbital
- D. atomic volume becomes zero
Explanation: Nuclear charge rises while added electrons go into same shell.
Diagonal relation
14. Lithium shows diagonal relationship mainly with:
- A. magnesium (Correct)
- B. beryllium
- C. aluminium
- D. sodium
Explanation: Lithium and magnesium share some anomalous similarities.
Anomalies
15. Electron gain enthalpy of chlorine is more negative than fluorine mainly because:
- A. fluorine is too small and has greater interelectronic repulsion (Correct)
- B. chlorine has lower nuclear charge
- C. fluorine is metallic
- D. chlorine has fewer electrons
Explanation: Compact 2p orbitals in fluorine create repulsion for the incoming electron.
Blocks
16. Elements in which the last electron enters a p-orbital belong to:
- A. p-block (Correct)
- B. s-block
- C. d-block
- D. f-block
Explanation: Block classification depends on the differentiating electron.
Blocks
17. Alkali metals belong to:
- A. group 1 (Correct)
- B. group 2
- C. group 17
- D. group 18
Explanation: They have outer configuration ns$^1$.
Noble gases
18. Noble gases are least reactive mainly because they have:
- A. stable electronic configurations (Correct)
- B. largest atomic radii
- C. lowest ionization enthalpy
- D. high metallic character
Explanation: Their valence shells are complete.
Isoelectronic trend
19. Among isoelectronic species, size decreases with increasing:
- A. nuclear charge (Correct)
- B. mass number
- C. number of neutrons
- D. shell number
Explanation: Greater nuclear pull contracts the electron cloud.
Concept summary
20. Periodic classification works because properties repeat after certain intervals due to repetition of:
- A. valence-shell electronic configuration (Correct)
- B. atomic mass only
- C. nuclear density
- D. crystal defects
Explanation: Chemical properties mainly depend on outer-electron arrangement.
Periodicity
21. The most electropositive element lies toward:
- A. bottom left of the periodic table (Correct)
- B. top right of the periodic table
- C. center of d-block
- D. noble gas corner
Explanation: Metallic and electron-losing tendency grows in that direction.
Periodicity
22. The most non-metallic elements lie toward:
- A. top right excluding noble gases (Correct)
- B. bottom left
- C. center of periodic table only
- D. f-block
Explanation: Non-metallic and electron-accepting character peaks there.
Screening
23. Shielding effect down a group increases because:
- A. number of inner shells increases (Correct)
- B. nuclear charge decreases
- C. valence electrons enter same shell
- D. mass stays constant
Explanation: More inner electrons screen outer ones.
Ionization anomaly
24. The first ionization enthalpy of oxygen is lower than nitrogen because oxygen has:
- A. paired electrons in one p-orbital causing repulsion (Correct)
- B. half-filled p-subshell stability
- C. larger size only
- D. fewer protons
Explanation: Nitrogen's half-filled p$^3$ configuration is especially stable.
Trend logic
25. The best single predictor of a periodic trend is the competition between effective nuclear charge and:
- A. shielding plus shell distance (Correct)
- B. bond enthalpy only
- C. pressure
- D. temperature
Explanation: Most periodic trends reduce to that balance.
Periodic law
26. Modern periodic law states that properties of elements are periodic functions of:
- A. atomic number (Correct)
- B. atomic mass
- C. neutron number
- D. molar mass
Explanation: Modern periodicity is based on atomic number.
Period
27. Horizontal rows in the periodic table are called:
- A. periods (Correct)
- B. groups
- C. blocks
- D. series
Explanation: Periods run left to right.
Group
28. Vertical columns in the periodic table are called:
- A. groups (Correct)
- B. periods
- C. blocks
- D. shells
Explanation: Groups contain chemically similar elements.
Atomic radius
29. Across a period, atomic radius generally:
- A. decreases (Correct)
- B. increases
- C. remains constant
- D. first increases then decreases
Explanation: Effective nuclear charge rises across a period.
Atomic radius
30. Down a group, atomic radius generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes zero
Explanation: Additional shells are added down a group.
Ionization enthalpy
31. Across a period, first ionization enthalpy generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes negative
Explanation: Smaller size and higher nuclear charge hold electrons more tightly.
Electron gain enthalpy
32. Halogens generally have:
- A. highly negative electron gain enthalpy (Correct)
- B. positive electron gain enthalpy
- C. zero electron gain enthalpy
- D. the lowest electronegativity
Explanation: They strongly attract an extra electron.
Electronegativity
33. Fluorine has the highest:
- A. electronegativity (Correct)
- B. atomic radius
- C. metallic character
- D. number of shells
Explanation: Fluorine is the most electronegative element.
Metallic character
34. Metallic character across a period generally:
- A. decreases (Correct)
- B. increases
- C. remains same
- D. becomes maximum in noble gases
Explanation: Elements become less willing to lose electrons.
Metallic character
35. Metallic character down a group generally:
- A. increases (Correct)
- B. decreases
- C. remains same
- D. becomes zero
Explanation: Larger atoms lose electrons more easily.
Valency
36. Valency across a period first increases and then:
- A. decreases (Correct)
- B. stays fixed
- C. becomes zero only
- D. doubles
Explanation: It follows the tendency to gain or lose electrons toward noble-gas configuration.
Oxides
37. Across a period, oxides generally change from:
- A. basic to acidic (Correct)
- B. acidic to basic
- C. neutral to metallic only
- D. basic to amphoteric to basic
Explanation: Metallic oxides are basic while non-metallic oxides are acidic.
Shielding
38. The main reason effective nuclear charge rises across a period is:
- A. shielding does not increase enough to offset nuclear charge (Correct)
- B. mass number increases only
- C. all electrons stay in same orbital
- D. atomic volume becomes zero
Explanation: Nuclear charge rises while added electrons go into same shell.
Diagonal relation
39. Lithium shows diagonal relationship mainly with:
- A. magnesium (Correct)
- B. beryllium
- C. aluminium
- D. sodium
Explanation: Lithium and magnesium share some anomalous similarities.
Anomalies
40. Electron gain enthalpy of chlorine is more negative than fluorine mainly because:
- A. fluorine is too small and has greater interelectronic repulsion (Correct)
- B. chlorine has lower nuclear charge
- C. fluorine is metallic
- D. chlorine has fewer electrons
Explanation: Compact 2p orbitals in fluorine create repulsion for the incoming electron.
Blocks
41. Elements in which the last electron enters a p-orbital belong to:
- A. p-block (Correct)
- B. s-block
- C. d-block
- D. f-block
Explanation: Block classification depends on the differentiating electron.
Blocks
42. Alkali metals belong to:
- A. group 1 (Correct)
- B. group 2
- C. group 17
- D. group 18
Explanation: They have outer configuration ns$^1$.
Noble gases
43. Noble gases are least reactive mainly because they have:
- A. stable electronic configurations (Correct)
- B. largest atomic radii
- C. lowest ionization enthalpy
- D. high metallic character
Explanation: Their valence shells are complete.
Isoelectronic trend
44. Among isoelectronic species, size decreases with increasing:
- A. nuclear charge (Correct)
- B. mass number
- C. number of neutrons
- D. shell number
Explanation: Greater nuclear pull contracts the electron cloud.
Concept summary
45. Periodic classification works because properties repeat after certain intervals due to repetition of:
- A. valence-shell electronic configuration (Correct)
- B. atomic mass only
- C. nuclear density
- D. crystal defects
Explanation: Chemical properties mainly depend on outer-electron arrangement.
Periodicity
46. The most electropositive element lies toward:
- A. bottom left of the periodic table (Correct)
- B. top right of the periodic table
- C. center of d-block
- D. noble gas corner
Explanation: Metallic and electron-losing tendency grows in that direction.
Periodicity
47. The most non-metallic elements lie toward:
- A. top right excluding noble gases (Correct)
- B. bottom left
- C. center of periodic table only
- D. f-block
Explanation: Non-metallic and electron-accepting character peaks there.
Screening
48. Shielding effect down a group increases because:
- A. number of inner shells increases (Correct)
- B. nuclear charge decreases
- C. valence electrons enter same shell
- D. mass stays constant
Explanation: More inner electrons screen outer ones.
Ionization anomaly
49. The first ionization enthalpy of oxygen is lower than nitrogen because oxygen has:
- A. paired electrons in one p-orbital causing repulsion (Correct)
- B. half-filled p-subshell stability
- C. larger size only
- D. fewer protons
Explanation: Nitrogen's half-filled p$^3$ configuration is especially stable.
Trend logic
50. The best single predictor of a periodic trend is the competition between effective nuclear charge and:
- A. shielding plus shell distance (Correct)
- B. bond enthalpy only
- C. pressure
- D. temperature
Explanation: Most periodic trends reduce to that balance.
Periodic law
51. Modern periodic law states that properties of elements are periodic functions of:
- A. atomic number (Correct)
- B. atomic mass
- C. neutron number
- D. molar mass
Explanation: Modern periodicity is based on atomic number.
Period
52. Horizontal rows in the periodic table are called:
- A. periods (Correct)
- B. groups
- C. blocks
- D. series
Explanation: Periods run left to right.
Group
53. Vertical columns in the periodic table are called:
- A. groups (Correct)
- B. periods
- C. blocks
- D. shells
Explanation: Groups contain chemically similar elements.
Atomic radius
54. Across a period, atomic radius generally:
- A. decreases (Correct)
- B. increases
- C. remains constant
- D. first increases then decreases
Explanation: Effective nuclear charge rises across a period.
Atomic radius
55. Down a group, atomic radius generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes zero
Explanation: Additional shells are added down a group.
Ionization enthalpy
56. Across a period, first ionization enthalpy generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes negative
Explanation: Smaller size and higher nuclear charge hold electrons more tightly.
Electron gain enthalpy
57. Halogens generally have:
- A. highly negative electron gain enthalpy (Correct)
- B. positive electron gain enthalpy
- C. zero electron gain enthalpy
- D. the lowest electronegativity
Explanation: They strongly attract an extra electron.
Electronegativity
58. Fluorine has the highest:
- A. electronegativity (Correct)
- B. atomic radius
- C. metallic character
- D. number of shells
Explanation: Fluorine is the most electronegative element.
Metallic character
59. Metallic character across a period generally:
- A. decreases (Correct)
- B. increases
- C. remains same
- D. becomes maximum in noble gases
Explanation: Elements become less willing to lose electrons.
Metallic character
60. Metallic character down a group generally:
- A. increases (Correct)
- B. decreases
- C. remains same
- D. becomes zero
Explanation: Larger atoms lose electrons more easily.
Valency
61. Valency across a period first increases and then:
- A. decreases (Correct)
- B. stays fixed
- C. becomes zero only
- D. doubles
Explanation: It follows the tendency to gain or lose electrons toward noble-gas configuration.
Oxides
62. Across a period, oxides generally change from:
- A. basic to acidic (Correct)
- B. acidic to basic
- C. neutral to metallic only
- D. basic to amphoteric to basic
Explanation: Metallic oxides are basic while non-metallic oxides are acidic.
Shielding
63. The main reason effective nuclear charge rises across a period is:
- A. shielding does not increase enough to offset nuclear charge (Correct)
- B. mass number increases only
- C. all electrons stay in same orbital
- D. atomic volume becomes zero
Explanation: Nuclear charge rises while added electrons go into same shell.
Diagonal relation
64. Lithium shows diagonal relationship mainly with:
- A. magnesium (Correct)
- B. beryllium
- C. aluminium
- D. sodium
Explanation: Lithium and magnesium share some anomalous similarities.
Anomalies
65. Electron gain enthalpy of chlorine is more negative than fluorine mainly because:
- A. fluorine is too small and has greater interelectronic repulsion (Correct)
- B. chlorine has lower nuclear charge
- C. fluorine is metallic
- D. chlorine has fewer electrons
Explanation: Compact 2p orbitals in fluorine create repulsion for the incoming electron.
Blocks
66. Elements in which the last electron enters a p-orbital belong to:
- A. p-block (Correct)
- B. s-block
- C. d-block
- D. f-block
Explanation: Block classification depends on the differentiating electron.
Blocks
67. Alkali metals belong to:
- A. group 1 (Correct)
- B. group 2
- C. group 17
- D. group 18
Explanation: They have outer configuration ns$^1$.
Noble gases
68. Noble gases are least reactive mainly because they have:
- A. stable electronic configurations (Correct)
- B. largest atomic radii
- C. lowest ionization enthalpy
- D. high metallic character
Explanation: Their valence shells are complete.
Isoelectronic trend
69. Among isoelectronic species, size decreases with increasing:
- A. nuclear charge (Correct)
- B. mass number
- C. number of neutrons
- D. shell number
Explanation: Greater nuclear pull contracts the electron cloud.
Concept summary
70. Periodic classification works because properties repeat after certain intervals due to repetition of:
- A. valence-shell electronic configuration (Correct)
- B. atomic mass only
- C. nuclear density
- D. crystal defects
Explanation: Chemical properties mainly depend on outer-electron arrangement.
Periodicity
71. The most electropositive element lies toward:
- A. bottom left of the periodic table (Correct)
- B. top right of the periodic table
- C. center of d-block
- D. noble gas corner
Explanation: Metallic and electron-losing tendency grows in that direction.
Periodicity
72. The most non-metallic elements lie toward:
- A. top right excluding noble gases (Correct)
- B. bottom left
- C. center of periodic table only
- D. f-block
Explanation: Non-metallic and electron-accepting character peaks there.
Screening
73. Shielding effect down a group increases because:
- A. number of inner shells increases (Correct)
- B. nuclear charge decreases
- C. valence electrons enter same shell
- D. mass stays constant
Explanation: More inner electrons screen outer ones.
Ionization anomaly
74. The first ionization enthalpy of oxygen is lower than nitrogen because oxygen has:
- A. paired electrons in one p-orbital causing repulsion (Correct)
- B. half-filled p-subshell stability
- C. larger size only
- D. fewer protons
Explanation: Nitrogen's half-filled p$^3$ configuration is especially stable.
Trend logic
75. The best single predictor of a periodic trend is the competition between effective nuclear charge and:
- A. shielding plus shell distance (Correct)
- B. bond enthalpy only
- C. pressure
- D. temperature
Explanation: Most periodic trends reduce to that balance.
Periodic law
76. Modern periodic law states that properties of elements are periodic functions of:
- A. atomic number (Correct)
- B. atomic mass
- C. neutron number
- D. molar mass
Explanation: Modern periodicity is based on atomic number.
Period
77. Horizontal rows in the periodic table are called:
- A. periods (Correct)
- B. groups
- C. blocks
- D. series
Explanation: Periods run left to right.
Group
78. Vertical columns in the periodic table are called:
- A. groups (Correct)
- B. periods
- C. blocks
- D. shells
Explanation: Groups contain chemically similar elements.
Atomic radius
79. Across a period, atomic radius generally:
- A. decreases (Correct)
- B. increases
- C. remains constant
- D. first increases then decreases
Explanation: Effective nuclear charge rises across a period.
Atomic radius
80. Down a group, atomic radius generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes zero
Explanation: Additional shells are added down a group.
Ionization enthalpy
81. Across a period, first ionization enthalpy generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes negative
Explanation: Smaller size and higher nuclear charge hold electrons more tightly.
Electron gain enthalpy
82. Halogens generally have:
- A. highly negative electron gain enthalpy (Correct)
- B. positive electron gain enthalpy
- C. zero electron gain enthalpy
- D. the lowest electronegativity
Explanation: They strongly attract an extra electron.
Electronegativity
83. Fluorine has the highest:
- A. electronegativity (Correct)
- B. atomic radius
- C. metallic character
- D. number of shells
Explanation: Fluorine is the most electronegative element.
Metallic character
84. Metallic character across a period generally:
- A. decreases (Correct)
- B. increases
- C. remains same
- D. becomes maximum in noble gases
Explanation: Elements become less willing to lose electrons.
Metallic character
85. Metallic character down a group generally:
- A. increases (Correct)
- B. decreases
- C. remains same
- D. becomes zero
Explanation: Larger atoms lose electrons more easily.
Valency
86. Valency across a period first increases and then:
- A. decreases (Correct)
- B. stays fixed
- C. becomes zero only
- D. doubles
Explanation: It follows the tendency to gain or lose electrons toward noble-gas configuration.
Oxides
87. Across a period, oxides generally change from:
- A. basic to acidic (Correct)
- B. acidic to basic
- C. neutral to metallic only
- D. basic to amphoteric to basic
Explanation: Metallic oxides are basic while non-metallic oxides are acidic.
Shielding
88. The main reason effective nuclear charge rises across a period is:
- A. shielding does not increase enough to offset nuclear charge (Correct)
- B. mass number increases only
- C. all electrons stay in same orbital
- D. atomic volume becomes zero
Explanation: Nuclear charge rises while added electrons go into same shell.
Diagonal relation
89. Lithium shows diagonal relationship mainly with:
- A. magnesium (Correct)
- B. beryllium
- C. aluminium
- D. sodium
Explanation: Lithium and magnesium share some anomalous similarities.
Anomalies
90. Electron gain enthalpy of chlorine is more negative than fluorine mainly because:
- A. fluorine is too small and has greater interelectronic repulsion (Correct)
- B. chlorine has lower nuclear charge
- C. fluorine is metallic
- D. chlorine has fewer electrons
Explanation: Compact 2p orbitals in fluorine create repulsion for the incoming electron.
Blocks
91. Elements in which the last electron enters a p-orbital belong to:
- A. p-block (Correct)
- B. s-block
- C. d-block
- D. f-block
Explanation: Block classification depends on the differentiating electron.
Blocks
92. Alkali metals belong to:
- A. group 1 (Correct)
- B. group 2
- C. group 17
- D. group 18
Explanation: They have outer configuration ns$^1$.
Noble gases
93. Noble gases are least reactive mainly because they have:
- A. stable electronic configurations (Correct)
- B. largest atomic radii
- C. lowest ionization enthalpy
- D. high metallic character
Explanation: Their valence shells are complete.
Isoelectronic trend
94. Among isoelectronic species, size decreases with increasing:
- A. nuclear charge (Correct)
- B. mass number
- C. number of neutrons
- D. shell number
Explanation: Greater nuclear pull contracts the electron cloud.
Concept summary
95. Periodic classification works because properties repeat after certain intervals due to repetition of:
- A. valence-shell electronic configuration (Correct)
- B. atomic mass only
- C. nuclear density
- D. crystal defects
Explanation: Chemical properties mainly depend on outer-electron arrangement.
Periodicity
96. The most electropositive element lies toward:
- A. bottom left of the periodic table (Correct)
- B. top right of the periodic table
- C. center of d-block
- D. noble gas corner
Explanation: Metallic and electron-losing tendency grows in that direction.
Periodicity
97. The most non-metallic elements lie toward:
- A. top right excluding noble gases (Correct)
- B. bottom left
- C. center of periodic table only
- D. f-block
Explanation: Non-metallic and electron-accepting character peaks there.
Screening
98. Shielding effect down a group increases because:
- A. number of inner shells increases (Correct)
- B. nuclear charge decreases
- C. valence electrons enter same shell
- D. mass stays constant
Explanation: More inner electrons screen outer ones.
Ionization anomaly
99. The first ionization enthalpy of oxygen is lower than nitrogen because oxygen has:
- A. paired electrons in one p-orbital causing repulsion (Correct)
- B. half-filled p-subshell stability
- C. larger size only
- D. fewer protons
Explanation: Nitrogen's half-filled p$^3$ configuration is especially stable.
Trend logic
100. The best single predictor of a periodic trend is the competition between effective nuclear charge and:
- A. shielding plus shell distance (Correct)
- B. bond enthalpy only
- C. pressure
- D. temperature
Explanation: Most periodic trends reduce to that balance.
Periodic law
101. Modern periodic law states that properties of elements are periodic functions of:
- A. atomic number (Correct)
- B. atomic mass
- C. neutron number
- D. molar mass
Explanation: Modern periodicity is based on atomic number.
Period
102. Horizontal rows in the periodic table are called:
- A. periods (Correct)
- B. groups
- C. blocks
- D. series
Explanation: Periods run left to right.
Group
103. Vertical columns in the periodic table are called:
- A. groups (Correct)
- B. periods
- C. blocks
- D. shells
Explanation: Groups contain chemically similar elements.
Atomic radius
104. Across a period, atomic radius generally:
- A. decreases (Correct)
- B. increases
- C. remains constant
- D. first increases then decreases
Explanation: Effective nuclear charge rises across a period.
Atomic radius
105. Down a group, atomic radius generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes zero
Explanation: Additional shells are added down a group.
Ionization enthalpy
106. Across a period, first ionization enthalpy generally:
- A. increases (Correct)
- B. decreases
- C. remains constant
- D. becomes negative
Explanation: Smaller size and higher nuclear charge hold electrons more tightly.
Electron gain enthalpy
107. Halogens generally have:
- A. highly negative electron gain enthalpy (Correct)
- B. positive electron gain enthalpy
- C. zero electron gain enthalpy
- D. the lowest electronegativity
Explanation: They strongly attract an extra electron.
Electronegativity
108. Fluorine has the highest:
- A. electronegativity (Correct)
- B. atomic radius
- C. metallic character
- D. number of shells
Explanation: Fluorine is the most electronegative element.
Metallic character
109. Metallic character across a period generally:
- A. decreases (Correct)
- B. increases
- C. remains same
- D. becomes maximum in noble gases
Explanation: Elements become less willing to lose electrons.
Metallic character
110. Metallic character down a group generally:
- A. increases (Correct)
- B. decreases
- C. remains same
- D. becomes zero
Explanation: Larger atoms lose electrons more easily.
Valency
111. Valency across a period first increases and then:
- A. decreases (Correct)
- B. stays fixed
- C. becomes zero only
- D. doubles
Explanation: It follows the tendency to gain or lose electrons toward noble-gas configuration.
Oxides
112. Across a period, oxides generally change from:
- A. basic to acidic (Correct)
- B. acidic to basic
- C. neutral to metallic only
- D. basic to amphoteric to basic
Explanation: Metallic oxides are basic while non-metallic oxides are acidic.
Shielding
113. The main reason effective nuclear charge rises across a period is:
- A. shielding does not increase enough to offset nuclear charge (Correct)
- B. mass number increases only
- C. all electrons stay in same orbital
- D. atomic volume becomes zero
Explanation: Nuclear charge rises while added electrons go into same shell.
Diagonal relation
114. Lithium shows diagonal relationship mainly with:
- A. magnesium (Correct)
- B. beryllium
- C. aluminium
- D. sodium
Explanation: Lithium and magnesium share some anomalous similarities.
Anomalies
115. Electron gain enthalpy of chlorine is more negative than fluorine mainly because:
- A. fluorine is too small and has greater interelectronic repulsion (Correct)
- B. chlorine has lower nuclear charge
- C. fluorine is metallic
- D. chlorine has fewer electrons
Explanation: Compact 2p orbitals in fluorine create repulsion for the incoming electron.
Blocks
116. Elements in which the last electron enters a p-orbital belong to:
- A. p-block (Correct)
- B. s-block
- C. d-block
- D. f-block
Explanation: Block classification depends on the differentiating electron.
Blocks
117. Alkali metals belong to:
- A. group 1 (Correct)
- B. group 2
- C. group 17
- D. group 18
Explanation: They have outer configuration ns$^1$.
Noble gases
118. Noble gases are least reactive mainly because they have:
- A. stable electronic configurations (Correct)
- B. largest atomic radii
- C. lowest ionization enthalpy
- D. high metallic character
Explanation: Their valence shells are complete.
Isoelectronic trend
119. Among isoelectronic species, size decreases with increasing:
- A. nuclear charge (Correct)
- B. mass number
- C. number of neutrons
- D. shell number
Explanation: Greater nuclear pull contracts the electron cloud.
Concept summary
120. Periodic classification works because properties repeat after certain intervals due to repetition of:
- A. valence-shell electronic configuration (Correct)
- B. atomic mass only
- C. nuclear density
- D. crystal defects
Explanation: Chemical properties mainly depend on outer-electron arrangement.
Periodicity
121. The most electropositive element lies toward:
- A. bottom left of the periodic table (Correct)
- B. top right of the periodic table
- C. center of d-block
- D. noble gas corner
Explanation: Metallic and electron-losing tendency grows in that direction.
Periodicity
122. The most non-metallic elements lie toward:
- A. top right excluding noble gases (Correct)
- B. bottom left
- C. center of periodic table only
- D. f-block
Explanation: Non-metallic and electron-accepting character peaks there.
Screening
123. Shielding effect down a group increases because:
- A. number of inner shells increases (Correct)
- B. nuclear charge decreases
- C. valence electrons enter same shell
- D. mass stays constant
Explanation: More inner electrons screen outer ones.
Ionization anomaly
124. The first ionization enthalpy of oxygen is lower than nitrogen because oxygen has:
- A. paired electrons in one p-orbital causing repulsion (Correct)
- B. half-filled p-subshell stability
- C. larger size only
- D. fewer protons
Explanation: Nitrogen's half-filled p$^3$ configuration is especially stable.
Trend logic
125. The best single predictor of a periodic trend is the competition between effective nuclear charge and:
- A. shielding plus shell distance (Correct)
- B. bond enthalpy only
- C. pressure
- D. temperature
Explanation: Most periodic trends reduce to that balance.