Carboxylic acid propertiesMediumQuestion 790006
Question
Carboxylic acids have higher boiling points than alcohols of similar molecular weight because:
- AThey form stronger H-bonded dimersCorrect
- BThey are ionic
- CThey have higher molar mass always
- Dvan der Waals forces are stronger
Correct answer
They form stronger H-bonded dimers
Explanation
Carboxylic acids form cyclic H-bonded dimers through two strong O−H···O hydrogen bonds. This effective doubling of molecular mass significantly raises boiling points.