JEE AdvancedHardQuestion 790011
Question
Rosenmund reduction of acid chloride (RCOCl + H₂, Pd/BaSO₄) gives:
- AAldehyde (RCHO)Correct
- BCarboxylic acid
- CAlcohol
- DAlkane
Correct answer
Aldehyde (RCHO)
Explanation
Rosenmund reduction: RCOCl + H₂ → RCHO (aldehyde). The poisoned catalyst (Pd/BaSO₄) prevents further reduction of the aldehyde to alcohol. Used for preparing aldehydes from acid chlorides.