JEE AdvancedHardQuestion 820010
Question
Carbylamine reaction (formation of isocyanide) is a test for:
- APrimary amines only (1°)Correct
- BSecondary amines
- CTertiary amines
- DAll amines
Correct answer
Primary amines only (1°)
Explanation
Carbylamine test: 1° amine + CHCl₃ + KOH/NaOH → isocyanide (R−NC) with extremely foul smell. This is a specific test for primary amines. 2° and 3° amines do not give this reaction.