JEE AdvancedHardQuestion 860009
Question
Among 3d transition metals, the one with the highest number of unpaired electrons is:
- ACr (3d⁵4s¹, 6 unpaired total)Correct
- BMn (3d⁵4s², 5 unpaired in d)
- CFe (3d⁶4s², 4 unpaired)
- DCu (3d¹⁰4s¹, 1 unpaired)
Correct answer
Cr (3d⁵4s¹, 6 unpaired total)
Explanation
Cr: [Ar]3d⁵4s¹ → 5 unpaired in 3d + 1 in 4s = 6 total unpaired electrons. Mn has 5d + 2s electrons but the 4s are paired → 5 unpaired. So Cr has most unpaired e⁻ among 3d metals.