Alkene additionEasyQuestion 770002
Question
Markovnikov's rule predicts that in HX addition to CH₂=CHCH₃:
- AH adds to CH₂ (less substituted C) and X to CH (more substituted C)Correct
- BX adds to CH₂ and H to CH
- CEqual amounts of both products
- DNo reaction
Correct answer
H adds to CH₂ (less substituted C) and X to CH (more substituted C)
Explanation
Markovnikov's rule: H adds to the carbon with more H atoms (less substituted). The more stable (more substituted) carbocation intermediate forms: CH₃−CH⁺−CH₃ (2°) rather than CH₃−CH−CH₂⁺ (1°).