JEE AdvancedHardQuestion 770011
Question
Cyclopentadienyl anion (C₅H₅⁻) is aromatic because:
- AIt has 6 π electrons satisfying Hückel's rule (4n+2, n=1)Correct
- BIt has 5 π electrons
- CIt has 4 π electrons
- DCyclic conjugation alone makes it aromatic
Correct answer
It has 6 π electrons satisfying Hückel's rule (4n+2, n=1)
Explanation
C₅H₅⁻ has 5 carbons, 4 π electrons from double bonds + 1 lone pair from the carbanion = 6 π electrons total. Hückel's rule: 4n+2 = 6 (n=1). Cyclic, planar, fully conjugated + 6π electrons → aromatic.