Ionisation energyMediumQuestion 840004
Question
The first ionisation energy (IE₁) generally increases:
- AAcross a period and up a groupCorrect
- BDown a group and across a period
- COnly down a group
- DOnly across a period
Correct answer
Across a period and up a group
Explanation
IE₁ increases: (1) across a period — higher Zeff, smaller radius; (2) up a group — smaller atoms, valence electrons closer to nucleus. Exceptions: Group 13 (IE < Group 2 due to 2p vs 2s), Group 16 (IE < Group 15 due to e⁻-e⁻ repulsion in paired orbital).