MixedHardQuestion 880008
Question
Bleaching powder (CaOCl₂ or Ca(OCl)Cl) on treatment with CO₂ releases:
- ACl₂ gas (which does the bleaching)Correct
- BCO₂ remains unchanged
- CCaCO₃ + HCl
- DCa(OH)₂ + Cl₂
Correct answer
Cl₂ gas (which does the bleaching)
Explanation
Bleaching powder + dilute acid/CO₂: Ca(OCl)Cl + CO₂ + H₂O → CaCO₃ + Cl₂ + H₂O (or with HCl → CaCl₂ + H₂O + Cl₂). The liberated Cl₂ oxidises coloured matter → bleaching. The reaction with CO₂ in air explains why bleaching powder loses potency on storage.