Hydrogen bonding effectMediumQuestion 600332
Question
HF has a higher boiling point than HCl because:
- AHF has higher molar mass
- BHF has stronger intermolecular H-bondingCorrect
- CHF is more ionic
- DHF has weaker London forces
Correct answer
HF has stronger intermolecular H-bonding
Explanation
F is the most electronegative element → H−F bonds are highly polar → strong intermolecular H-bonding in HF. HCl has no significant H-bonding. Hence HF has an anomalously high boiling point.