Benzene reactionsEasyQuestion 770004
Question
Benzene undergoes electrophilic substitution (NOT addition) because:
- AAddition would destroy aromaticity (stability)Correct
- BBenzene has no double bonds
- CElectrophiles cannot add
- DAromatic compounds are unreactive
Correct answer
Addition would destroy aromaticity (stability)
Explanation
Benzene's aromatic stabilisation energy (~150 kJ/mol) would be lost in addition reactions. Substitution restores aromaticity while addition would not. This thermodynamic preference drives EAS over addition.